There is no such thing as 'natural nail polish'. Even the ones available that tout they are all natural water based polish are fibbing because they still contain plastics/chemicals of some sort.
Here are two companies that sell them (be sure to read the plus' and minus' and disclaimers they provide too):
And here are two recipes for homemde natural polish 'stain':
http://lifestyle.iloveindia.com/lou ... -natural-fingernail-polish-8146.html
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