If the area around you toilet is tiled then you will need to clean the grouted area often. If left too long urine can stain grout and will smell bad as well. This is a guide about cleaning urine off grout.
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I have ceramic tile floors, off-white grout and a little boy with bad aim. The grout has become heavily stained and I'm having trouble cleaning it. I have tried plain water, vinegar, oxy clean, and bleach without good results.