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Do not use bleach to get out rust stains. It sets rust. Watch those cleaners with bleach additives.
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Here are questions related to Removing Rust Stains from Fabric and Clothing.
How do I remove rust from cotton pants?
By Josie from Melbourne, Australia
I had two small rust spots on a white cotton sweater. I used Bar Keeper's liquid cleaner on it. I dabbed it on and let it sit a day and then laundered as usual. It didn't harm the fabric and completely removed the stain.
How do I remove rust spots from garments?
I agree with Jsham, Whink is the way to go...a wonderful product.
How can I remove rust marks on my nearly new white Anorak winter coat? Please help.
By Brandy J.06/23/2011
I once lived in a house with a well that had terrible amounts of iron in the water. I discovered a product called Iron Out. I found it in the hardware department of Walmart. It is safe to use on clothing. I would just follow the directions on the packaging. I used a half cup in my laundry, but I remember there were other directions for spot use.
How do you remove rust from the neck of a white shirt? The hanger it was on in the closet broke and rust from the metal part got on the neck of my white Sunday shirt.
By Earl from Moriarty, NM
Pour lemon juice on the rust spot and allow the shirt to sit in direct sunlight for at least 20 minutes. Rinse and launder as usual. Repeat if necessary.