Just tried regular rubbing alcohol that you find in the medicine cabinet, (70%), alcohol content. I poured it right on the black stain and blotted with white paper towels. Got out the black shoe dye....yes dye, out in seconds. Come to think of it there is a dye remover wherever you find shoe dye to prep the shoes when dyeing them. That will probably do a nice job as well.
Janice, I've got a husband in the military so I feel for you. If I catch it right away I can get them out with white vinegar and water. 3/4 vinegar and 1/4 water. I hope this helps you.
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