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If you are ever stung by a fire ant, use vinegar to stop the itch..
Being new to Florida I have found this really works.
I've always used Hydrogen Peroxide to treat fire ant stings. It immediately takes the sting out and helps the white looking sore heal up very fast. My husband, being from the country, taught me this when we got married. I didn't think it would work until I tried it and it really does work.
I've always found that stepping on the little bugger and then running like heck has always worked for me. ANd when I've finished cursing I put hydrogen peroxide on it followed up with calamine lotion.