Preheat oven to 350 degrees F. grease 10 inch Bundt pan and lightly flour. Sift flour, baking powder, baking soda, and salt. Combine sugar, brown sugar, shortening, and peanut butter in large bowl. Beat on low speed until creamy. Add eggs (1 at a time). Add vanilla and mix well. Add dry ingredients and milk. Spoon 2 cups batter into bowl and add chocolate syrup; mix. Spoon remaining batter into Bundt pan. Spoon chocolate batter over the peanut butter batter. Bake 1 hour and 10 minutes. Cool 45 minutes in pan. Mix glaze and pour on cake (add water to thin).
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