Buy the loose catnip in a bag at the store and scatter it around when you have them out together. I never force cats together. The scared newcomer will stay in the bathroom until it develops skills and confidence to approach not only humans but other cats.
I have found the bathroom an excellent hideaway for kittens/cats who need to develop socialization skills. You go in there many times a day and go out. It is great for the cats.
I was watching my newer cat laying near one of my dogs when I gave her a catnip toy I just had received from a friend in the mail. She relaxed. It was so funny. Don't leave them together, until you are sure they are getting along.
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