What you are looking at is SOOT from the fire, not smoke. That takes a much different cleaning tool. To remove smoke or other smells, just put the toys in a pillow case, pin shut with safety pins, and wash as usual, air dry then toss into dryer 10 minutes to fluff.
I have a white beanie baby that gets regular cigarette smoke film on it from time to time. I just put it in a pillowcase and tie a tight knot in the top of the pillowcase and throw it in the washer. I remove it immeditatly from the washer and pillowcase when the cycle is done and brush the fur back into place with my hand and let air dry. You could never tell she's had a "bath" every 6 months for the last 6 years.
I collect teddy bears and pick them up at garage sales and all of them go into the washing machine with warm water and any laundry detergent, do not dry them in the dryer hang out side to dry then fluff in the dryer and they are just like new. The heat of the dryer seems to singe the material. Good luck Beanie babies come out beautifull.
Build-a-Bear (www.buildabear.com) sells a GREAT stuffed animal cleaner that really works, & it is inexpensive!
They say you can put silk flowers in a bag with baking (or washing) soda and shake to remove dust. Wouldn't hurt to try. Then you could use a nozzle on the vac to remove left overs.
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